[736]

D. Dhara, L. Endres, A. Roy, R. D. Dewhurst, R. Bertermann, F. Fantuzzi, H. Braunschweig

A Discrete Trialane with a Near-Linear Al₃ Axis

J. Am. Chem. Soc. 2024, 146, 33536–33542. [pdf]

[735]

F. Zhang, V. Brancaccio, F. Saal, U. Deori, K. Radacki, H. Braunschweig, P. Rajamalli, P. Ravat

Ultra-Narrowband Circularly Polarized Luminescence from Multiple 1,4-Azaborine-Embedded Helical Nanographenes

J. Am. Chem. Soc. 2024, 146, 29782–29791. [pdf]

[734]

V. Malhotra, B. J. Elvers, R. Dolai, N. Chrysochos, S. S. M. Bandaru, T. Gangber, N. J. Britto, I. Krummenacher, G. Rajaraman, H. Braunschweig, C. Schulzke, A. Jana

Cross-Coupling of NHC/CAAC-Based Carbodicarbene: Synthesis of Electron-Deficient Diradicaloids

J. Am. Chem. Soc. 2024, 146, 29481–29490. [pdf]

[733]

L. Euringer, M. Holzapfel, I. Krummenacher, M. Franz, S. Richert, H. Braunschweig, C. Lambert

Tuning Electron Transfer Coupling and Exchange Interaction in Bis-triarylamine Radical Cations and Dications by Bridge Electron Density

J. Am. Chem. Soc. 2024, 146, 27679–27689. [pdf]

[732]

C. Luz, K. Oppel, R. D. Dewhurst, H. Braunschweig, U. Radius

Construction of a Boron Chain on a Single Metal by Dehydrocoupling of Borane Ligands

J. Am. Chem. Soc. 2024, 146, 23741–23751. [pdf]

[731]

L. Wu, X. Zhang, M. Moos, I. Krummenacher, M. Dietz, A. Jayaraman, R. Bertermann, Q. Ye, M. Finze, M. Wenzel, R. Mitric, C. Lambert, H. Braunschweig, L. Ji

Full Electron Delocalization across the Cluster in 1,12-bisBMes₂-p-carborane Radical Anion

J. Am. Chem. Soc. 2024, 146, 17956–17963. [pdf]

[730]

M. Rang, M. Heinz, A. Halkić, M. Weber, R. D. Dewhurst, A. Rempel, M. Härterich, M. C. Holthausen, H. Braunschweig

Trapping of a Terminal Intermediate in the Boron-Mediated Dinitrogen Reduction: Mono‑,Tri‑, and Tetrafunctionalized Hydrazines in Two Steps from N₂

J. Am. Chem. Soc. 2024, 146, 11048–11053. [pdf]

[729]

A. Das, B. J. Elvers, N. Chrysochos, S. I. Uddin, T. Gangber, I. Krummenacher, D. Borah, A. Mishra, M. Shanmugam, C. B. Yildiz, H. Braunschweig, C. Schulzke, A. Jana

Dianionic and Neutral Diboron-Centered Classical Diradicaloids
J. Am. Chem. Soc. 2024, 146, 9004–9011. [pdf]

[728]

S. Dotzauer, A. Jayaraman, D. Reinhart, H. Braunschweig

Intermolecular 1,2-Aminoboration of Alkynes and the Critical Role of Electron-Rich Alkynes

Angew. Chem. 2024, 136, e202413370; Angew. Chem. Int. Ed. 2024, 63, e202413370. [pdf]

[727]

A. Jayaraman, B. Ritschel, M. Arrowsmith, C. Markl, M. Jürgensen, A. Halkić, Y. Konrad, A. Stoy, K. Radacki, H. Braunschweig

Experimental Observation of a Terminal Borylene-Dinitrogen Adduct via Cleavage of a 1,2,3,4,5-Diboratriazoline

Angew. Chem. 2024, 136, e202412307;  [pdf] Angew. Chem. Int. Ed. 2024, 63, e202412307. [pdf]

[726]

L. Walther, K. Radacki, R. D. Dewhurst, R. Bertermann, M. Finze, H. Braunschweig

All-Inorganic sp-Chain Ligands: Isoelectronic B/N Analogues of E. O. Fischer's Alkynylcarbynes

Angew. Chem. 2024, 136, e202404930; [pdf] Angew. Chem. Int. Ed. 2024, 63, e202404930. [pdf]

[725]

M. Weber, T. Kupfer, M. Arrowsmith, R. D. Dewhurst, M. Rang, B. Ritschel, S. Titlbach, M. Ernst, M. Oliveira Rodrigues, E. N. da Silva Júnior, H. Braunschweig

Bypassing Ammonia: From N₂ to Nitrogen Heterocycles without N₁ Intermediates or Transition Metals

Angew. Chem. 2024, 136, e202402777; [pdf] Angew. Chem. Int. Ed. 2024, 63, e202402777. [pdf]

[724]

C. Czernetzki, T. Kunz, S. Huynh, A. Lamprecht, J. Sprenger, M. Finze, M. Arrowsmith, H. Braunschweig

Synthesis and Reactivity of Tricoordinate Organoberyllium Azides

Angew. Chem. 2024, 136, e202401279; [pdf] Angew. Chem. Int. Ed. 2024, 63, e202401279. [pdf]

[723]

D. Dhara, L. Endres, I. Krummenacher, M. Arrowsmith, R. D. Dewhurst, B. Engels, R. Bertermann, M. Finze, S. Demeshko, F. Meyer, F. Fantuzzi, H. Braunschweig

Synthesis and Reactivity of a Dialane-Bridged Diradical

Angew. Chem. 2024, 136, e202401052; [pdf] Angew. Chem. Int. Ed. 2024, 63, e202401052. [pdf]

[722]

M. Arrowsmith, H. Braunschweig

Peter Paetzold (1935‒2023): a Chemist of Many Talents

Angew. Chem. 2024, 136, e202319179; [pdf] Angew. Chem. Int. Ed. 2024, 63, e202319179. [pdf]

[721]

S. Koushik, H. Braunschweig

Characterization of a secondary carbon-centred radical

Nature Synth. 2024, 3, 677–678. [link]

[720]

N. Wieprecht, I. Krummenacher, L. Wüst, M. Michel, S. Fuchs, S. Nees, M. Härterich, H. Braunschweig

The forgotten borole: synthesis, properties and reactivity of a 1-boraindene

Chem. Sci. 2024, 15, 12496-12501. [pdf]

[719]

A. Swain, K. Radacki, H. Braunschweig, P. Ravat

Helically twisted nanoribbons via stereospecific annulative π-extension reaction employing [7]helicene as a molecular wrench

Chem. Sci. 2024, 15, 11737-11747. [pdf]

[718]

J. Krebs, L. Brändler, I. Krummenacher, A. Friedrich, H. Braunschweig, M. Finze, B. F. E. Curchod, T. B. Marder

Synthesis, Photophysical and Electronic Properties of a D-π-A Julolidine-Like Pyrenyl-o-Carborane

Chem. Eur. J. 2024, 30, e202401704. [pdf]

[717]

P. Mentzel, M. Holzapfel, A. Schmiedel, J. Günther, M. Michel, I. Krummenacher, A. Wodyński, M. Kaupp, H. Braunschweig, C. Lambert

Structure and Photophysics of N-Tolanyl-phenochalcogenazines and their Radical Cations
Chem. Eur. J. 2024, 30, e202303782. [pdf]

[716]

Í. A. O. Bozzi, L. A. Machado, E. B. T. Diogo, F. G. Delolo, L. O. F. Barros, G. A. P. Graça, M. H. Araujo, F. T. Martins, L. F. Pedrosa, L. C. da Luz, F. S. Rodembusch, J. S. F. Guimarães, A. G. Oliveira, S. Röttger, D. B. Werz, C. P. Souza, F. Fantuzzi, T. B. Marder, H. Braunschweig, E. N. da Silva Júnior

Electrochemical Diselenation of BODIPY Fluorophores for Bioimaging Applications and Sensitization of ¹O₂

Chem. Eur. J. 2024, 30, e202303883. [pdf]

[715]

J. L. Bohlen, N. Wieprecht, M. Arrowsmith, A. Häfner, M. Neder H. Braunschweig

One-step selective synthesis of doubly and triply fused chiral boroloborole derivatives

Chem. Commun. 2024, 60, 14782-14785. [pdf]

[714]

M. S. Luff, K. Oppel, I. Krummenacher, H. Braunschweig, U. Radius

Radical anions of 1,1-azoliumdithiocarboxylates

Chem. Commun. 2024, 60, 14447-14450. [pdf]

[713]

R. Witte, S. Kar, K. Radacki, M. Härterich, M. Rang, M. Michel, C. Mihm, C. Czernetzki, T. Brückner, E. Beck, S. Lutz, R. D. Dewhurst, H. Braunschweig

Transition-metal-like coordination chemistry of dicoordinate borylenes with organic azides

Chem. Commun. 2024, 60, 8629-8632. [pdf]

[712]

T. Brückner, D. Duwe, F. Fantuzzi, M. Heß, R. D. Dewhurst, K. Radacki, H. Braunschweig

Hydrosilylation of B-B Triple Bonds: Catalyst- and Reductant-Free Construction of B–Si bonds and B₂Si Heterocycles

Chem. Commun. 2024, 60, 3259-3262. [pdf]

[711]

M. K. Nayak, B. J. Elvers, S. Mehta, I. Krummenacher, A. Mondal, H. Braunschweig, C. Schulzke, P. Ravat, A. Jana

Bis-[cyclic(alkyl)(amino)carbene]s-derived diradicals

Chem. Commun. 2024, 60, 1739-1742. [pdf]

[710]

D. Duwe, K. Saha, L. Endres, T. Brückner, R. D. Dewhurst, M. Dietz, K. Radacki, F. Fantuzzi, H. Braunschweig

Stepwise and selective synthesis of chelating, multimetallic and mixed-metal π-diborene complexes

Chem. Commun. 2024, 60, 1120-1123. [pdf]

[709]

M. Passargus, M. Arrowsmith, R. Bertermann, M. Finze, H. Braunschweig

A-Frame-Templated High-Coordinate Platinum(IV) cis-Bis(boryl) Complexes

Inorg. Chem. 2024, 63, 10657–10670. [pdf]

[708]

C. Czernetzki, M. Arrowsmith, L. Endres, I. Krummenacher, H. Braunschweig

Tricoordinate Beryllium Radicals and Their Reactivity
Inorg. Chem. 2024, 63, 2670–2678. [pdf]

[707]

C. Czernetzki, M. Arrowsmith, M. Jürgensen, S. Hagspiel, H. Braunschweig

Synthesis and structures of molecular beryllium Grignard analogues featuring terminal and bridging pseudohalides

Dalton Trans. 2024, 53, 18296-18303. [pdf]

[706]

A. Lamprecht, M. Arrowsmith, M. Dietz, S. Fuchs, A. Rempel, M. Härterich, H. Braunschweig

Synthesis, reduction and C‒H activation chemistry of azaborinines with redox-active organoboryl substituents

Dalton Trans. 2024, 53, 1004-1013. [pdf]

[705]

M. Dietz, M. Arrowsmith, H. Braunschweig

CAAC-stabilised 9,10-diboraanthracene: an electronically and structurally flexible platform for small-molecule activation and metal complexation
Dalton Trans. 2024, 53, 449-453. [pdf]

[704]

J. Cui, Y. He, C. P. Souza, J. Weiser, M. Dietz, I. Krummenacher, R. D. Dewhurst, H. Braunschweig, F. Fantuzzi

Single-Electron Oxidation, Chloride Abstraction, and Hydride-Induced Decomposition of a Dichloro-Bis(Germylene)

Eur. J. Inorg. Chem. 2024, 27, e202400422. [pdf]